Yasuda, Masahide

Professor

Department of Applied Chemistry, University of Miyazaki

Gakuen-Kibanadai, Miyazaki-889-2192, Japan

Research interests are the environmental conscious photochemical synthetic methods and the developments of materials having new photochemical functionality

$$ Born in 1953 at Wakayama Pref. in Japan
$$ BA, Osaka University (R. Okawara Lab.) in 1976
$$ PhD, Osaka University (H. Sakurai & C. Pac Group) in 1981
$$ Research Associate, Miyazaki University, in 1984
$$ Professor, University of Miyazaki from 2000

Award for Young Chemist from the Kyushu/Yamaguchi Branch, The Society of Synthetic Organic Chemistry, Japan in 1987

Fax   +81-985-58-7315
E-mail: yasuda@cc.miyazaki-u.ac.jp
Web: http://www.crc.miyazaki-u.ac.jp/y1ken/

Our research objects is to elucidate the photochemical properties of metalloporphyrin complexes having the functionalized axial ligands and to develop the photochemical synthetic method as environmentally friendly synthetic processes.

Last update January 18, 2013

Lists of Papers

業績(原著論文・総説・著書)

1978

l   Reductant-Induced Homolysis of the Thallium-Carbon Bond: Novel Oxygenation of Alkyl- thallium (III) Compounds with Ascorbic Acid, H. Kurosawa and M. Yasuda, J. Chem. Soc. Chem. Comm., 1978, 716-717

 

1

1979

 

0

1980

l   Homolysis of the Tl-C Bond in Hydrodethallation of Alkylthallium(III) Compounds with N- Benzyl-1,4-dihydronicotinamide, H. Kurosawa, H. Okada, and M. Yasuda, Tetrahedron Lett., 21. 959-960 (1980)

l   Photoreactions of 1-Cyanonaphthalene with Indene in Various Solvents, M. Yasuda, C. Pac, and H. Sakurai, Bull. Chem. Soc. Jpn., 53, 502-507 (1980)

2

1981

l   Direct Photocyanation of Arenes with Sodium Cyanide in the Presence of Electron Acceptors, M. Yasuda, C. Pac, and H. Sakurai, J. Chem. Soc., Perkin Trans. 1, 1981, 746-750

l   Photo-Birch Reduction of Arenes with Sodium Borohydride in the Presence of Dicyanobenzene, M. Yasuda, C. Pac, and H. Sakurai, J. Org. Chem., 46, 788 ?792 (1981)

l   The Photoreactions of Anthracene with Some Selected Tertiary Aromatic Amines in Polar Media, M. Yasuda, C. Pac, and H. Sakurai, Bull. Chem. Soc. Jpn., 54, 2352- 2355 (1981)

l   Ru(bpy)32+-Mediated Photoreduction of Olefins with 1-Benzyl-1,4-dihydronicotinamide: A Mechanistic Probe for Electron-Transfer Reaction of NAD(P)H-Model Compounds, C. Pac, M. Ihama, M. Yasuda, Y. Miyauchi, and H. Sakurai, J. Am. Chem. Soc., 103, 6495-6497 (1981)

4

1982

l   Solvent Effects on Fluorescence Quenching and Photoreactions of Naphthalene- Olefin and Furan Systems. Qualitative Consideration on Electronic Structures and Reactivities of Nonemissive Exciplexes, C. Pac, M. Yasuda, K. Shima, and H. Sakurai, Bull. Chem. Soc, Jpn., 55, 1605-1616 (1982)

1

1983

 

0

1984

l   Ru(bpy)32+-Photosensitized Reactions of 1-Benzyl-1,4-dihydronicotinamide with Ary-Substituted Enones, Derivatives of Methyl Cinnamate, and Substituted Cinnamonitriles: Electron-Transfer Mechanism and Structure-Reactivity Relationships, C. Pac, Y. Miyauchi, O. Ishitani, M. Ihama, M. Yasuda, and H. Sakurai, J. Org. Chem., 49, 26-34 (1984)

1

1985

l   [1] Synthetic Application of Photochemical Electron Transfer to Direct Amination of Arenes by Ammonia and Primary Amines, M. Yasuda, T. Yamashita, T. Matsumoto, K. Shima, and C. Pac, J. Org. Chem., 50, 3667-3669 (1985)

 

1

1986

l   [2] Acid-Catalysed Rearangements of [4.3.2]- and [3.3.3]Propellanes Tricyclo- [4.3.2.01,5]undecanes, and Tricyclo[6.3.0.01,5]undecanes, K. Kakiuchi, M. Ue, I. Wakaki, Y. Tobe, Y. Odaira, M. Yasuda, and K. Shima, J. Org. Chem., 51, 281-287 (1986)

 

1

1987

l   [3] Direct Photoamination of Arenes with Ammonia and Primary Amines in the Presence of Electron Acceptors, M. Yasuda, T. Yamashita, K. Shima, and C. Pac, J. Org. Chem., 52, 753-759 (1987)

l   [総説] Direct Introduction of Functional Groups to Aromatic Nuclei by Photo- chemical Electron Transfer, M. Yasuda and K. Shima, Memoirs of the Faculty of Eng., Miyazaki Univ., 17, 1 (1987)

 

2

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1988

l   [4] Mechanisms for Direct Photoamination of Arenes with Ammonia and Amines in the Presence of m-Dicyanobenzene, M. Yasuda, Y. Matsuzaki, K. Shima, and C. Pac, J. Chem. Soc. Perkin Trans. 2, 1988, 745-751

l   [5] Solvolytic Rearrangement of 5,6-Polymethylenebicyclo[4.2.0]octan-2-ol Deriva- tives to Functionalized Polymethylenebicyclo[3.2.1]- and [3.3.0]octanes, M. Ue, T. Nagashima, M. Kinugawa, K. Kakiuchi, Y. Tobe, Y. Odaira, M. Yasuda, and K. Shima, Chem. Lett., 1988, 1521-1522

 

2

1989

l   [6] Photosensitized Ring-Cleavage Reactions of 2,2-Diaryloxetanes by Aromatic Nitriles, K. Nakabayashi, J. Kojima, K. Tanabe, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 62, 96-101 (1989)

l   [7] Salt-Induced Photoamination of Arenes by Aliphatic Amines via Arene/p-Dicyanobenzene Exciplexes. A Mechanism for Salt Effects on Charge Separation of Exciplexes, M. Yasuda, Y. Matsuzaki, T. Yamashita, and K. Shima, Chem. Lett., 1989, 551-554

l   [8] Novel Rearrangement of 5,6-Disubstituted Bicyclo[4.2.0]octan-2-ones with AlCl3. Application to Total Synthesis of (±)-5-Oxosilphiperfol-6-ene and (±)-Silphiperfol- 6-ene, K. Kakiuchi, M. Ue, H. Tsukahara, T. Shimizu, T. Miyao, Y. Tobe, Y. Odaira, M. Yasuda, and K. Shima, J. Am. Chem. Soc., 111, 3707-3712 (1989)

l   [9] Molecular Structures of Diarylcyclobutanes Associated with Reactivities in Ring- Cleavage Reactions: Implications of Conformationally Controlled Through-Bond Coupling, K. Shima, J. Kimura, K. Yoshida, M. Yasuda, K. Imada, and C. Pac, Bull. Chem. Soc. Jpn., 62, 1934 ?1942 (1989)

l   [10] Thermal Ring-Splitting Reactions of Diarylcyclobutanes: Significance of Steric Effects on Orbital Interactions in Transition States and Biradical Intermediates, M. Yasuda, K. Yoshida, K. Shima, C. Pac, and S. Yanagida, Bull. Chem. Soc. Jpn., 62, 1943-1950 (1989)

l   [11]エキシプレックスを経由するフェナントレンの光アミノ化反応に対する塩効果の速度論的解析, 保田昌秀,松崎頼明,山下敏明,志摩健介,日本化学会誌1989, 1292-1298

l   [12] Photochemical Ring-Cleavage Reactions of 2,2-Diaryloxetanes in the Presence of Electron Donor, K. Nakabayashi, S. Fujimura, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 62, 2733-2735 (1989)

l   [総説] 光電子移動反応による活性化ー芳香核と求核試剤との反応, 保田昌秀,化学と工業,42, 74-78 (1989)

l   [非審査] TiO2-SiO2系多孔質ガラスセラミックスを光触媒とする2-プロパノールの脱水素反応志摩健介,保田昌秀,藤井基志,宮崎大学工学部研究報告35, 25 (1989)

l   [非審査] 光電子移動反応を経由するフェナントレン類のアンモニアおよびアミンによる直接的光アミノ化反応 に対する溶媒効果、保田昌秀,水谷学,松崎頼明,山下敏明,志摩健介,旭硝子工業技術奨励会研究報告54, 263 (1989)

 

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1990

l   [13] Direct Phosphonation of Naphthalene and Phenanthrene with Trialkyl Phosphites via Photochemical Electron Transfer, M. Yasuda, T. Yamashita, and K. Shima, Bull. Chem. Soc., Jpn., 63, 938-940 (1990)

l   [14] Synthesis of Isoquinoline Precursors by Photoamination of Stilbenes with Bifunctional Alkylamines, M. Yasuda, J. Kubo, and K. Shima, Heterocycles, 31, 1007-1010 (1990)

l   [非審査] ナフトアルデヒド類の2,3-ジメチル-2-ブテンへの光付加ならびに生成オキセタンの光誘起環開裂反応、志摩健介,保田昌秀,田辺公子,中林健一,宮崎大学工学部研究報告36, 23 (1990)

l   [非審査] 低極性溶媒中での芳香族炭化水素の光アミノ化反応 .エキシプレックスの電荷分離に対する塩効果,保田昌秀,渡辺康博,山下敏明,志摩健介,旭硝子財団研究報告,56, 103 (1990)

 

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1991

l   [15] Photoinduced Nucleophilic Addition of Ammonia and Alkylamines to Aryl-Substituted Alkenes in the Presence of p-Dicyanobenzene, T. Yamashita, K. Shiomori, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 64, 366-374 (1991)

l   [16] Unusual Effects of Acetate Ion on Photosensitized Oxygenation of Naphthalene Derivatives via Electron Transfer, T. Yamashita, T. Tsurusako, M. Yasuda, and K. Shima, Chem. Lett., 1991, 1487-1490

l   [総説] Amination of Electron-Rich Substrates via Photoinduced Electron Transfer: Mechanism and Synthetic Application, M. Yasuda and K. Shima, Reviews on Heteroatom Chemistry, 4, 27-46 (1991)

l   [総説] Synthetic Application of Photochemical Electron Transfer: Photoamination of Electron-Rich Substrates, M. Yasuda, T. Yamashita, and K. Shima, Memoirs of the Faculty of Eng., Miyazaki Univ., 20, 1 (1991)

 

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1992

l   [17] Regiochemistry on Photoamination of Stilbene Derivatives with Ammonia via Electron Transfer, M. Yasuda, T. Isami, J. Kubo, M. Mizutani, T. Yamashita, and K. Shima, J. Org. Chem., 57, 1351-1354 (1992)

l   [18] Stereochemical Studies on the Amination of Arenes with Ammonia and Alkylamines via Photochemical Electron Transfer, M. Yasuda, K. Shiomori, S. Hamasuna, K. Shima, and T. Yamashita, J. Chem. Soc. Perkin Trans. 2, 1992, 305-310

l   [19] Cycloreversion of 1,4-Diphenylbicyclo[3.2.0]hept-2-ene under Triplet Sensitization. An Adiabatic Process on the Triplet Surface, K. Nakabayashi, W. Fukumoto, M. Yasuda, K. Shima, and S. Takamuku, Chem. Lett., 1992, 803-806

l   [20] Application of Photoamination to Synthesis of Benzylisoquinoline, Aporphins, and Isopavines, M. Yasuda, S. Hamasuna, K. Yamano, J. Kubo, and K. Shima, Heterocycles, 34, 965-977 (1992)

l   [21] Ring-Splitting Reaction of 2,2-Diarylthietane by Electron-Transfer Photosensiti- zation of 9,10-Dicyanoanthracene, K. Shima, A. Sazaki, K. Nakabayashi, and M. Yasuda, Bull. Chem. Soc. Jpn., 65, 1472-1474 (1992)

l   [22] Efficient Cross-Photocycloadditions of Vinylcoumarins to Olefins, M. Yasuda, T. Kishi, C. Goto, H. Satoda, K. Nakabayashi, T. Minami, and K. Shima, Tetrahedron Lett., 33, 6465-6468 (1992)

l   [23] Photochemical Reactions of 1,4-Dicyanonaphthalene with Allylic Silanes: Control of Reaction Modes by Use of Solvent and Additive Effects, K. Mizuno, K. Terasaka, T. Nishiyama, M. Yasuda, K. Shima, T. Tamai, and Y. Otsuji, Tetrahedron, 48, 9673-9686 (1992)

l   [非審査] サイクリックボルタンメトリーによるスチルベン類および芳香族炭化水素の酸化電位の測定, 保田昌秀,諌見俊洋,久仏由佳,志摩健介,宮崎大学工学部研究報告38, 53 (1992)

l   [非審査] ノルボルナジエン,クワドリシクランへのピルビン酸メチルの光付加, 志摩健介,保田昌秀,田辺公子, 宮崎大学工学部研究報告38, 61 (1992)

 

9

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1993

l   [24] Electron-Transfer Photosensitized Oxygenation of Stilbene and Naphthalene Derivatives in the Presence of Acetate Ion. Controlling the Reaction of the Cation Radicals by Weak-Nucleophilic Salts, T. Yamashita, T. Tsurusako, N. Nakamura, M. Yasuda, and K. Shima, Bull, Chem. Soc. Jpn., 66, 857-862 (1993)

l   [25] Cycloreversion of Aryl-Substituted Cyclobutene by Direct Photolysis and Pulse Radiolysis, K. Nakabayashi, Y. Tahara, M. Yasuda, K. Shima, and S. Takamuku, Bull. Chem. Soc. Jpn., 66, 698-702 (1993)

l   [26] A Convenient Method for Synthesis of 1-Amino-2-tetralones by Photoamination of 2-Alkoxynaphthalenes with Alkylamines, T. Yamashita, K. Yamano, M. Yasuda, and K. Shima, Chem. Lett., 1993, 627-630

l   [27] Dehydroamination Reactions of 9-Amino-9,10-dihydrophenanthrene and Related Compounds by Thermolysis, M. Yasuda, T. Harada, Y. Ansho, and K. Shima, Bull. Chem. Soc. Jpn., 66, 1451-1455 (1993)

l   [28] Synthesis of Phenylethylamine Moiety by Photoamination of Styrene Derivatives with Ammonia, T. Yamashita, M. Yasuda, T. Isami, S. Nakazono, K. Tanabe, and K. Shima, Tetrahedron Lett., 34, 5131-5134 (1993)

l   [29] Mechanistic Studies for Cross-Photocycloadditions of 3-Vinylcoumarin Derivativres to Electron-Rich Olefins, M. Yasuda, T. Kishi, C. Goto, H. Satoda, and K. Shima, J. Photochem. Photobiol. A: Chem., 76, 61-67 (1993)

l   [総説] Application of Photoinduced Nucleophilic Addition Reaction to Organic Synthesis, M. Yasuda and K. Shima, Trends in Organic Chemistry, 4, 291-302 (1993)

l   [総説] Organic Reactions Induced by Photochemical Electron Transfer: Ring-Cleavage Reaction of Small Ring Compounds by Photochemical Electron Transfer, M. Yasuda, K. Nakabayashi, and K. Shima, Memoirs of the Faculty of Eng., Miyazaki Univ., 22, 1 (1993)

 

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1994

l   [30] Photoamination of 2-Alkoxynaphthalenes with Alkylamines via Electron Transfer and Its Application to Synthesis of 1-Alkylamino-2-tetralones, T. Yamashita, K. Tanabe, K. Yamano, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 67, 246-250 (1994).

l   [31] Highly Twisted tert-Butoxycarbonyl in Hexa-tert-Butyl Benzenehexacarboxylate. The Structural Origin of Steric Hindrance-Induced Dual Fluorescence, M. Yasuda, G. Kuwamura, T. Nakazono, K. Shima, Y. Inoue, N. Yamasaki, and A. Tai, Bull. Chem. Soc. Jpn., 67, 505-510 (1994)

l   [32] Amination of o-Alkenylphenols with Alkylamines via Photoinduced Proton Transfer, M. Yasuda, T. Sone, K. Tanabe, and K. Shima, Chem. Lett., 1994, 453-456

l   [33] Regiochemistry on Photoamination of Methoxy-Substituted Phenanthrene via Electron Transfer, M. Yasuda, Y. Watanabe, K. Tanabe, and K. Shima, J. Photochem. Photobiol. A: Chem., 79, 61-65 (1994)

l   [34] Photoinduced Nucleophilic Addition of Ammonia and Alkylamines to Methoxy-Substituted Styrene Derivatives, T. Yamashita, M. Yasuda, T. Isami, K. Tanabe, and K. Shima, Tetrahedron, 50, 9275-9286 (1994)

l   [その他] 植物の初期生育に与える水の影響. I, 田辺公子, 新村恭弘、保田昌秀、志摩健介、中村 博、石川勝美, 植物工場学会誌、6, 147-152 (1994)

 

6

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1995

l   [35] Fluorescence study on polar intramolecular exciplexes of (p-phenanthroxy)alkyl p-cyanobenzoates, M. Yasuda, G. Kuwamura, and K. Shima, J. Photochem. Photobiol. A: Chem., 86, 127-131 (1995)

l   [36] Photochemical Reactions of o-Alkenylphenols and 1-Alkenyl-2-naphthol with Alkylamines: Amination via Photoinduced Proton transfer, M. Yasuda, T. Sone, K. Tanabe, and K. Shima, J. Chem. Soc. Perkin Trans. 1, 1995, 459-464

l   [37] Remarkable Effects of Surfactant on Flavin Photochemistry: Monomerization of Thymine Cyclobutane Dimers Photosensitized by Flavins in the Presence of SDS in Aqueous Solution, M. Yasuda, T.Nakazono, T. Hamasaki, Y. Nishinaka, N. Nakamura, C. Pac, and K. Shima, Chem. Lett., 1995, 563-564

l   [38] New Synthetic Route to Dibenzo[a,d]cycloheptenimines through Photoamination of 5-Alkoxy- and 5-Hydroxysibenzo[a,d]cycloheptenes Follwed by Trasannular Reaction with Acetic Acid, M. Yasuda, T. Wakisaka, R. Kojima, K. Tanabe, and K. Shima, Bull. Chem. Soc. Jpn., 68, 3169-3173 (1995)

l   [非審査] Photoinduced Nucleophilic Addition of Ammonia and Alkylamines to Methoxy- Substituted Stilbene and Styrene Derivatives: Additive Effect of p-Donor to the Reaction Efficiency, M. Yasuda, T. Yamashita, K. Tanabe, and K. Shima, Memoirs of the Faculty of Eng., Miyazaki Univ., 24, 1 (1995)

l   [その他] 植物の初期生育に与える水の影響 (第2報),田辺公子, 脇坂智子、保田昌秀、志摩健介、石川勝美,植物工場学会誌、7, 185-190 (1995)

l   [その他] 化学物質と環境、保田昌秀、会報(財)宮崎県公害防止管理協会 82号、26-32(1995)

 

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1996

l   [39] Cycloreversion of 1-(1-Naphtyl)-5-phenylbicyclo[3.2.0]hept-6-ene to 1-(1-Naphtyl)- 4-phenyl-1,3-cycloheptadiene by Triplet Sensitization and Direct Irradiation, K. Nakabayashi, J. Arimura, M. Yasuda, K. Shima, and S. Takamuku, Bull. Chem. Soc. Jpn., 69, 1313-1317 (1996)

l   [40] A Novel Type of Cyanomethylation Reaction of Diarylethenes with Acetonitrile Photosensitized by Benzophenone in the Presence of t-Butylamine, T. Yamashita, M. Yasuda, M. Watanabe, R. Kojima, K. Tanabe, and K. Shima, J. Org. Chem., 64, 6438-6441 (1996)

l   [総説] Photoamination Directed toward the Synthesis of Heterocyclic Compounds, M. Yasuda, T. Yamashita, R. Kojima, and K. Shima, Heterocycles, 43, 2513-2522 (1996)

 

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1997

l   [41] Regioselective 1,4-Addition of Ammonia to 1-Aryl-1,3-alkadienes and 1,4-Diaryl-1,3- butadienes via Photoinduced Electron Transfer, R. Kojima, T. Yamashita, K. Tanabe, T. Shiragami, M. Yasuda, and K. Shima, J. Chem. Soc. Perkin Trans. 1, 1997, 217-222

l   [42] Intramolecular Cyclization of 1,2-Distyrylbenzene via Cation Radical Generated by Photoinduced Electron Transfer, R. Kojima, T. Shiragami, K. Shima, M. Yasuda, and T. Majima, Chem. Lett., 1997, 1241-1242

2

1998

l   [43] Photochemistry of Flavins in Micelles: Specific Effects of Anionic Surfactants on the Monomerization of Thymine Cyclobutane Dimers Photosensitized by Tetra-O-acylriboflavins, M. Yasuda, Y. Nishinaka, T. Nakazono, T. Hamasaki, N. Nakamura, T. Shiragami, C. Pac, and K. Shima, Photochem. Photobiol., 1998, 67, 192- 197

l   [44] A Carbon-Centered Radical as a Reaction Species in the DNA Strand-Breakage by D-Glucosamine, T. Yamaguchi, N. Kashige, S. Matsumoto, K. Satoh, M. Yasuda, and K. Watanabe, Biol. Pham. Bull., 1998, 21, 205-209.

l   [45] Photoamination of Alkenylnaphthalene with Ammonia via Electron Transfer, M. Yasuda, R. Kojima, R. Ohira, T. Shiragami, and K. Shima, Bull. Chem. Soc. Jpn., 71, 1655-1660 (1998)

l   [46] Benzophenone-Photosensitized Alkylation of Arylalkenes with Acetone, Dimethyl Sulfoxide, and their Related Compounds in the Presence of tert-Butylamine, T. Yamashita, M. Watanabe, R. Kojima, T. Shiragami, K. Shima, and M. Yasuda, J. Photochem. Photobiol. A: Chem., 118, 165-171 (1998)

l   [その他] 植物の初期生育に与える水の影響. (第3報),田辺公子, 首藤里香、森山 昌、白上 努、志摩健介、保田昌秀、志摩健介、石川勝美, 植物工場学会誌、10, 79-83 (1998)

 

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1999

l   [47] Solvent Parameter Based on the Exciplex Emission of (2-Naphthoxy)polyalkyl p-Cyanobenzoates, M. Yasuda, Y. Kawahito, K. Sasano, Y. Andou, T. Shiragami, and K. Shima, J. Photochem. Photobiol. A: Chem., 121, 149-155 (1999)

l   [48] Photoamination of 1,2-Diarylcyclopropanes Using 2,2'-Dialkoxy-1,1'-binaphthalene as Redox- Photosensitizer, M. Yasuda, R. Kojima, H. Tsutsui, L. A. Watanabe, J. Hobo, T. Yamashita, T. Shiragami, and K. Shima, Chem. Lett., 1999, 1269-1270

l   [総説]Photoamination via Electron Transfer, M. Yasuda, T. Yamashita, T. Shiragami, and K. Shima, Recent Reasearch Deveolpment in Photochemistry & Photobiology, 3 65-76 (1999)

l   [総説] 汎用性のある光化学反応をめざして:光アミノ化反応, 保田昌秀,志摩健介、光化学30, No. 3, 215-222 (1999)

 

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2000

 

0

2001

l   [49] A Novel (3+2) photocycloaddition of Electron-deficient Alkenes to Diarylvinyidene- cyclopropanes: Regioselective Formation of Vinylidene- cyclopentanes, K. Mizuno, H. Sugita, T. Hirai, H. Maeda, Y. Otsuji, M. Yasuda, M. Hashiguchi, and K. Shima, Tetrahedron Lett., 42, 3363-3366 (2001)

l   [50] Copper Biosorption by Chemically Treated Micrococcus luteus Cells, A. Nakajima, M. Yasuda, H. Yokoyama, H. Ohya-Nishiguchi, and H. Kamada, World J. Microbiology Biotechnology, 17, 343-347 (2001)

l   [51] Fluorescence Responses on Ion Recognition with 2-(4-Dialkylaminophenyl)ethoxy- antimony(V) Tetraphenylporphyrin, Y. Andou, K. Shima, T. Shiragami, and M. Yasuda, Chem. Lett., 2001, 1198-1199

l   [特許]アンチモンポルフィリン光触媒、保田昌秀、白上努、信原一敬、近藤徹、公開特許広報、特開2001-340761

l   光と化学の事典、分担執筆 保田昌秀、丸善(2001

 

5

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2002

l   [52] Synthesis and Fluorescence Study of (2-Naphthoxy)polyoxalkoxyantimony(V) Tetraphenylporphyrin Complex, Y. Andou, T. Shiragami, K. Shima, and M. Yasuda, J. Photochem. Photobiol. A: Chem. 147, 191-197 (2002)

l   [53] Effects of Axial Ligands on Reduction Potentials, Proton Dissociation, and Fluorescence Quantum Yield of Hydroxoporphyrinatoantimony(V) Complexes, T. Shiragami, Y. Andou, Y. Hamasuna, F. Yamaguchi, K. Shima, and M. Yasuda, Bull. Chem. Soc. Jpn., 75, 1577-1582 (2002)

l   [54] O-Alkylation of Dihydroxo(tetraarylporphyrinato)phosphorous(V) and Antimony (V) Complexes with Alkyl Halides, Y. Andou, K. Ishikawa, K. Shima, T. Shiragami, M. Yasuda, and H. Inoue, Bull. Chem. Soc. Jpn., 75, 1757-1760 (2002)

l   [特許] 光触媒装置、保田昌秀、白上努、信原一敬、笛田佳之、公開特許公報 特開2002-136879

l   [特許] 殺菌方法および殺菌装置、保田昌秀、白上 努、横井春比古、信原一敬、笛田佳之、特願2002-130611特開2003-320000

 

5

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2003

l   [55] Role of Axial Ligands on Intercalation of Cationic Metalloporphyrin into Smectite Cray Layers, T. Shiragami, K. Nabeshima, M. Yasuda, and H. Inoue, Chem. Lett., 32, 148-149 (2003)

l   [56] Micelle-Enhancing Effect on a Flavin-Photosensitized Reaction of Benzyl Alcohols in Aqueous Solution, M. Yasuda, T. Nakai, Y. Kawahito, and T. Shiragami, Bull. Chem. Soc. Jpn., 76, 601-605 (2003)

l   [57] Silica Gel-Supported Porphyrinatoantimony(V) Complex Acting as Visible-Light Driven Photocatalyst for Dechlorination of Chlorophenols in Aqueous Solution, T. Shiragami, Y. Shimizu, K. Hinoue, Y. Fueda, K. Nobuhara, I. Akazaki, and M. Yasuda, J. Photochem. Photobiol. A: Chem. 156, 115-119 (2003)

l   [58] Non-Aggregated Intercalation of Dicationic Tetraphenylporphyrinatoantimony(V) Complexes into Smectite Cray Layers, T. Shiragami, K. Nabeshima, J. Matsumoto, M. Yasuda, and H. Inoue, Chem. Lett., 32, 484-485 (2003)

l   [59] Bactericidal Effect of Silica Gel-Supported Porphyrinatoantimony(V) Complex under Visible-Light Irradiation, H. Yokoi, T. Shiragami, J. Hirose, T. Kawauchi, K. Hinoue, Y. Fueda, K. Nobuhara, I. Akazaki, and M. Yasuda, World J. Microbiology Biotechnology, 19, 559-563 (2003)

l   [60] Redox-Photosensitized amination of 1,2-Benzo-1,3-cycloalkadienes, Arylcyclopropanes and Quadrcyclane with Ammonia, M. Yasuda, R. Kojima, H. Tsutsui, D. Utsunomiya, K. Ishii, K. Jinouchi, and T. Shiragami, J. Org. Chem, 68, 7618-7624 (2003)

l   [総説] Photochemical Polar Addition, M. Yasuda and K. Mizuno, Handbook of Photochemistry and Photobiology, American Scientific Publishers, Vol. 2, 393-434 (2003)

l   [執筆] 実験化学講座 アルケン 分担執筆 保田昌秀 日本化学会編 丸善 (2003)

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2004

l   [61] Efficient Photocatalytic Oxidation of Cycloalkenes by Dihydroxo(tetraphenylporphyrinato)- antimony Suported on Silica Gel under Visible Light Irradiation, T. Shiragami, R. Makise, Y. Inokuchi, J. Matsumoto, H. Inoue, and  M. Yasuda, Chem. Lett.,, 33, 736-737 (2004)

 

1

 

2005

l   [62] Synthesis and spectroscopic analysis of tetraphenylporphyrinatoantimony(V) complexes linked to boron-dipyrrin chromophore on axial ligands T. Shiragami, K. Tanaka, Y. Andou, S. Tsunami, J. Matsumoto, H. Luo, Y. Araki, O. Ito, H. Inoue and M. Yasuda, J. Photochem. Photobiol. A: Chem. 170, 287-297 (2005). 

l   [63] Visible-light Bactericidal Effect of Silica Gel-supported Porphyrinatoantimony(V) Catalyst on Legionella Species Occurring in the Living Environmental Fields, Y. Fueda, M. Hsashimoto, K. Nobuhara, H. Yokoi, Y. Komiya, T. Shiragami, J. Matsumoto, K. Kawano, S. Suzuki, and M. Yasuda, Biocontrol Science, 10, 55 ?60 (2005).

l   [64] Generation of quinone methide from aminomethyl(hydroxy)arenes precursors in aqueous solution, J. Matsumoto, M. Ishidu, R. Kawano, D. Hesaka, T. Shiragami, Y. Hayashi, T. Yamashita, and M. Yasuda, Tetrahedron. 61 5735-5740 (2005).

l   [65] Confocal Laser Scanning Microscope Analysis of Antimony Porphyrin Chromophore Immobilized on Silica-Gel Beads, J. Matsumoto, T. Fuchikawa, Y. Komiya, Y. Fueda, T. Matsumoto, T. Shiragami, and M. Yasuda, Chem. Lett., 34, 1484-1485 (2005)

l   [66] Effects of Axial Ligands on the Formation of a Layered Structure in Mono- and Di-cationic Charged Tetraphenylporphyrinatoantimony(V)/Synthetic Clay Composites, T. Shiragami, K. Nabeshima, S. Nakashima, J. Matsumoto, S. Takagi, H. Inoue, and M. Yasuda, Bull. Chem. Soc. Jpn., 78, 2251-2258 (2005)

l   [総説] Photoamination with Ammonia and Amines, M. Yasuda, T. Shiragami, J. Matsumoto, K. Shima, and T. Yamashita, Organic Photochemistry and Photophysics ed. by V. Ramamurthy and K Schanze, CRC Press, Chapter 6, pp 207-253 (2005)

l   [総説] Antimony porphyrin complexes as visible-light driven photocatalyst, T. Shiragami, J. Matsumoto, H. Inoue, and M. Yasuda, J. Photochem. Photobiol. C: Review, 6, 227-248 (2005)

l   [その他]可視光触媒でレジオネラ属菌を殺菌、九州経済調査月報, 1月号、30-33(2005)

 

 

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2006

l   [67] Guamine-specific DNA damage photosensitized by dihydroxo(tetraphenylporphynato)- antimony(V) complex, K. Hirakawa, S. Kawanishi, J. Matsumoto, T. Shiragami, and M. Yasuda, J. Photochem. Photobiol. B: Biology 82, 37-44 (2006).

l   [68] Intramolecular electron transfer from axial ligand to S2-exited Sb-tetraphenylporphyrin, M. Fujitsuka, D.-W. Cho, T. Shiragami, M. Yasuda amd T. Majima, J. Phys. Chem. B: 110, 9368-9370 (2006)

l   [69] Bactericidal Effect of Silica Gel-Supported Porphyrinatophosphorus(V) Catalysts on Escherichia Coli under Visible Light Irradiation, Y. Fueda, H. Suzuki, Y. Komiya, Y. Asakura, T. Shiragami, J. Matsumoto, H. Yokoi, and M. Yasuda, Bull. Chem. Soc. Jpn., 79, 1420-1425 (2006)

l   [70] Non-aggregated adsorption of cationic metalloporphyrin dyes onto nano-clay sheets films T. Shiragami, Y. Mori, J. Matsumoto, S. Takagi, H. Inoue, and M. Yasuda, Colloid and Surface A: Physicochemical and Engineering Aspects., 284-285, 284-289 (2006)

 

4

 

 

 

 

 

2007

l   [71] Redox-Photosensitized Amination of alkenes and alkadienes with Ammonia and Alklyamines, T. Yamashita, J. Itagawa, D. Sakamoto, Y. Nakagawa, J. Matsumoto, T. Shiragami, M. Yasuda Tetrahedron.,63, 374-380 (2007)

l   [72] Effects of Axial Ligands on Intercalation of Tetraphenylporphyrinatoantimony(V) into Smectite Clay Layers, T. Shiragami, K. Nabeshima, J. Matsumoto, M. Yasuda, and H. Inoue, Res. Chem. Intermediate 33, 169-175 (2007).

l   [73] 噴水のレジオネラ属菌に対するシリカゲル担持リンポルフィリン光触媒を用いた太陽光殺菌実験、江馬 智, 柴田博文, 弥富勝美, 信原一敬, 笛田佳之, 松本 仁, 白上 努, 保田昌秀、防菌防黴学会誌, 35, 547-553 (2007)

l   [74] Porphyrin/MgCl2/Silica Gel Composite as a Cobalt-free Humidity Indicator, Y. Fueda, J. Matsumoto, T. Shiragami, K. Nobuhara, and M. Yasuda, Chem. Lett., 36 1246-1247 (2007)

l   [75] Electron Transfer from Axial Ligand to S1- and S2-Excited Phosphorus Tetraphenylporphyrin, M. Fujitsuka, D. W. Cho, S. Tojo, A. Inoue, T. Shiragami, M. Yasuda, and T. Majima, J. Phys. Chem.A: 111, 10574-10579 (2007)

l   [76] Silica gel supported photofunctional silicon phthalocyanine complexes: photodesprption of molecular oxygen by singlet oxygen generation, K. Ishii, M. Shiine, Y. Kikukawa, T. Shiragami, J. Matsumoto, M. Yasuda, H. Suzuki, and H. Yokoi, Chem Phys. Lett., 448, 264-267(2007).

l   [総説] アンチモンポルフィリン錯体の可視光触媒機能、保田昌秀、白上 努、松本 仁, 光化学, 38 9-14 (2007)

 

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2008

l   [77] Preparation and characterization of porphyrin chromophores immobilized on micro silica gel beads, J. Matsumoto, T. Matsumoto, Y. Senda, T. Shiragami, and M. Yasuda, J. Photochem. Photobiol. A: Chem. 197, 101-109 (2008)

l   [78] Effects of Axial Amino Ligand on Spectroscopic and Electrochemical Properties of Amino(methoxo)antimony(V) tetraphenylporphyrin Complexes S. Tsunami, K. Tanaka, J. Matsumoto, T. Shiragami, M. Yasuda, Bull. Chem. Soc. Jpn., 81,583-589 (2008)

l   [79] Water-soluble Porphyrin Easily Derived from Tetraphenylporphyrin: Alkyloxo(methoxo)- porphyrinatoantimony bromides, J. Matsumoto, T. Shiragami, and M. Yasuda, Chem. Lett., 37, 886-887 (2008)

l   [80] 共焦点レーザー走査型顕微鏡を用いる顕微吸光度分析, 松本朋子,白木隆一,松本 仁,白上 努,保田昌秀, 分析化学, 57, 819-824 (2008)

l   [81] Synthesis and Characterization of o-Hydroxybenzophenone Chromophore Bonded to Aminopropyl Silica Gel-Microbeads, Y. Senda, T. Hidaka, J. Matsumoto, T. Shiragami, M. Yasuda, Bull. Chem. Soc. Jpn., 81, 1518-1524 (2008)

l   [解説] 有機触媒で環境浄化、保田昌秀, 光と界面がおりなす新しい化学の世界、編集:高木克彦、大谷文章、早瀬修二、橋本和仁、瀬川浩司、矢作美紀子, 72-79,クバクロ(2008)

l   [解説] 金属ポルフィリン錯体の光触媒作用と応用展開、白上 努・保田昌秀, 光機能性高分子材料の新たな潮流―最新技術とその展望―, 25-36,シーエムシー(2008)

 

7

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2009

l   [82] 共焦点レ-ザー走査型顕微鏡を用いる酵母菌体へ吸着した水溶性ポルフィリン誘導体の吸光光度定量、松本朋子,中原卓郎,松本仁,白上努,保田昌秀、分析化学, 58, 357-361 (2009)

l   [83] Visible light-assisted sterilization activity of water-soluble antimonyporphyrin toward Saccharomyces cerevisiae, M. Yasuda, T. Nakahara, T. Matsumoto, T. Shiragami, J. Matsumoto, H. Yokoi, T. Hirano, K. Hirakawa, J. Photochem. Photobiol. A: Chem. 205, 210-214 (2009)

l   [84] Photolabile Protecting Group Bonded to Aminopropyl Silica-Gel Beads, J. Matsumoto, Y.  Senda, H. Masuda, T. Fuchikawa, T. Shiragami, and M. Yasuda, Bull. Chem. Soc. Jpn., 82, 997-999 (2009)

l   [85] Water-solubilization of alkyloxo(methoxo)porphyrinatoantimony bromides, J. Matsumoto, S. Tanimura, T. Shiragami, and M. Yasuda, Physical Chemistry Chemical Physics, 11, 9766-9771 (2009).

l   [総説] ポルフィリン型有機光触媒による可視光殺菌、保田昌秀、宮崎大学工学部紀要, 38, 1-12 (2009)

l   [非審査]光重合性リン脂質ジャイアントベシクルの作製と共焦点レーザー走査型顕微鏡分析、松本仁、米田幸志郎、白上努、保田昌秀、宮崎大学工学部紀要, 38, 73-78 (2009)

l   [解説]ポルフィリン型有機光触媒による可視光殺菌, 保田昌秀、白上 努、光科学研究の最前線2 197 強光子場科学研究懇談会(2009, 12)

 

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2010

l   [86] Amino(porphyrinato)antimony(V) Complexes as a Fluorosensor for Selective and Sensitive Detection of Trivalent Metal Cations, S. Tsunami, H. Fujiwara, J. Matsumoto, T. Shiragami and M. Yasuda, Bull. Chem. Soc. Jpn., 83, 49-51 (2010).

l   [87] Development of acyl-bonded aminopropyl silica gel-fillers with low interfacial adhesion energy in a polystyrene matrix, Y. Senda, T. Hidaka, J. Matsumoto, T. Shiragami, M. Yasuda, Polymer Journal, 42, 489-493 (2010).

l   [88] Di(hydroxo)porphyrin GeIV complex/silica gel composite as visible light-assisted radical generator, T. Shiragami, R. Shiraki, R. Makise, J. Matsumoto, and M. Yasuda, Chem. Lett., 39 874-875 (2010)

l   [89] Trialkyl(pentafluorocyclotriphosphazenyl)ammonium bis(trifluoromethylsulfonyl)imide Acting as Nonflammable Room Temperature Ionic Liquids, T. Shiragami, Y. Nakamura, J. Matsumoto, M. Ootsuki, and M. Yasuda, Chem. Lett. 39 1006-1007 (2010).

l   [90] Preparation and characterization of phase-segregated vesicles of photopolymerizable diacetylene mixed with non-polymerizable amphiphiles, J. Matsumoto, K. Yoneda, J. Tasaka, T. Shiragami, and M. Yasuda, Bull. Chem. Soc. Jpn, 83, 1551-1557 (2010).

l   [総説] 環境調和材料としての光機能性シリカゲルビーズ、保田昌秀、有機合成化学協会誌, 68, 238-246 (2010)

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2011

l   [91] Water-soluble phosphrous porphyrins with high activity for visible light-assisted inactivation of Saccharomyces cerevisiae, J. Matsumoto, T. Shinbara, S. Tanimura, T. Matsumoto, T. Shiragami, H. Yokoi, Y. Nosaka, S. Okazaki, K. Hirakawa, M. Yasuda, J. Photochem. Photobiol. A: Chem. 218, 178-184 (2011)

l   [92] Transformation of Glucose to 5-Hydroxymethyl-2-furfural by SiO2-MgCl2 Composite, M. Yasuda, Y. Nakamura, J. Matsumoto, H. Yokoi, and T. Shiragami, Bull. Chem. Soc. Jpn, 84, 416-418 (2011).

l   [93] The effect of TiO2-photocatalytic pretreatment on the biological production of ethanol from lignocelluloses, M. Yasuda, A. Miura, R. Yuki, Y. Nakamura, T. Shiragami, Y. Ishii, and H. Yokoi, J. Photochem. Photobiol. A: Chem. 220 195-199 (2011)

l   [94] Quantitative Analysis for a Color-Change of Humidity Indicator by Microscopic Absorption Spectrometry, T. Matsumoto, Y. Mitsumura, M. Miyamoto, J. Matsumoto, T. Shiragami, Y. Fueda, K. Nobuhara, and M. Yasuda, Analytical Science, 27, 623-628 (2011).

l   [95] Temperature Dependence of the Photo-sensitized Nucleophilic Addition to Alkenes, J. Matsumoto, Y. Yoshinaga, A. Hamasaki, T. Kawasaki, T. Yamashita, T. Shiragami, M. Yasuda, Bull. Chem. Soc. Jpn, 84, 1130-1132 (2011).

l   [非審査] 毛管浸透法による表面張力測定を利用したポリスチレンとヒドロキシベンゾフェノン固定化シリカゲルフィラー間の界面エネルギーの見積もり、保田昌秀, 西川僚寛, 日高貴弘,千田芳也, 松本 仁, 白上 努, 宮崎大学工学部紀要, 40, 23-28 (2011)

 

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2012

l   [96] Pentose acting as a sacrificial multi-electron source in photocatalytic hydrogen evolution from water by Pt-doped TiO2. T. Shiragami, T. Tomo, H. Tsumagari, R. Yuki, T. Yamashita, and M. Yasuda, Chem. Lett. 41, 29-31 (2012)

l   [97] Hydrogen evolution from napiergrass by the combination of biological treatment and a Pt-loaded TiO2-photocatalytic reaction, T. Shiragami, T. Tomo, H. Tsumagari, Y. Ishii, M. Yasuda, Catalyst, 2 56-67 (2012)

l   [98] Concentration-dependent aggregation of water-soluble phosphorous porphyrin in an aqueous solution, J. Matsumoto, S. Tanimura, T. Shiragami, and M. Yasuda, J. Porphyrins  Phthalocyanines, 16, 210-217 (2012)

l   [99] Ethanol production from non-pretreated napiergrass through a simultaneous saccharification and fermentation process followed by a pentose fermentation with Escherichia coli KO11, M. Yasuda, A. Miura, T. Shiragami, J. Matsumoto, I. Kamei, Y. Ishii, K. Ohta, J. Biol. Bioeng. 114, 188-192 (2012)

l   [100] Mechanistic analysis of the fluorescence quenching of dodecyloxo(methoxo)- tetraphenylporphyrinatoantimony by 9,10-dimethylanthracene in an artificial membrane constructed by a phospholipid liposome, J. Matsumoto, T. Beppu, T. Shiragami, and M. Yasuda, J. Photochem. Photobiol. A: Chem. 249, 47-52 (2012)

l   [101] ポルフィリンをpH指示薬に用いる顕微吸光光度分析によるマグネシウム塩―シリカゲル複合固体の酸性度測定、松本朋子,廣瀬大貴,山内彩香,松本 仁,白上 努,笛田佳之,保田昌秀、分析化学, 61, 851-856 (2012)

l   [102] Effectiveness of lignin-removal in simultaneous saccharification and fermentation of napiergrass, rice straw, silbergrass, and bamboo with different lignin-contents, M. Yasuda,a, K. Takeo, T. Matsumoto, T. Shiragami, Y. Matsushita, K. Sugamoto, and Y. Ishii, Sustainable Degradation of Lignocellulosic Biomass - Techniques, Applications and Commercialization, Edited by A. K. Chandel and S. Silverio da Silva, InTech.

l   [非審査] 草本系パルプの生化学反応および触媒反応によるバイオ燃料化、保田昌秀、中村泰久、三浦昭晃、松本朋子、松本仁、白上努, 宮崎大学工学部紀要, 41, 17-21 (2012)

 

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2013

l   [103] Controlling the photochemical reaction of alkenes by light-path length effects of micro- channel reactors, T. Yamashita, S. Matsushita, T. Nagatomo, R. Yamauchi, M. Yasuda, Res. Chem. Intermed 39, 111-126 (2013).

l   [104] Structural dependence of alcoholic sacrificial agents on TiO2-photocatalytic hydrogen evolution, T. Shiragami, T. Tomo, T. Matsumoto, and M. Yasuda, Bull. Chem. Soc. Jpn., xx, xxx-xxx (2012)

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